2,3-Dimethyl-N-[(E)-(1H-pyrrol-2-yl)methylidene]aniline

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2,3-Dimethyl-N-[(E)-(1H-pyrrol-2-yl)methyl­idene]aniline

In the title compound, C(13)H(14)N(2), the dihedral angle between the aromatic rings is 69.73 (14)°. In the crystal, inversion dimers linked by pairs of N-H⋯N hydrogen bonds generate R(2) (2)(10) loops. A weak C-H⋯π inter-action also occurs.

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2,5-Dimethyl-N-[1-(1H-pyrrol-2-yl)ethyl­idene]aniline

In the title compound, C(14)H(16)N(2), the pyrrole and benzene rings form a dihedral angle of 72.37 (8)°. In the crystal, centrosymmetrically related mol-ecules are assembled into dimers by by pairs of N-H⋯N hydrogen bonds, generating rings of R(2) (2)(10) graph-set motif. C-H⋯π inter-actions also occur.

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N′-[(E)-(1-Methyl-1H-pyrrol-2-yl)methyl­idene]benzohydrazide

In the title compound, C(13)H(13)N(3)O, the phenyl and pyrrole rings are inclined at 47.45 (8)°. In the crystal, inter-molecular N-H⋯O and C-H⋯O hydrogen bonds form R(2) (1)(6) ring motifs. Mol-ecules connected through these hydrogen bonds are arranged into polymeric chains extending along the c axis.

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(E)-2,4,6-Trimethyl-N-[(1H-pyrrol-2-yl)methyl­idene]aniline

The title compound, C14H16N2, is a pyrrole-2-carbaldimine ligand that shows an E conformation at the imine double bond. The dihedral angle between the rings is 78.3 (1)°. In the crystal, pairs of mol-ecules form centrosymmetric dimers [graph-set descriptor is presumably R(2)2(10)] via N-H⋯N hydrogen bonds between the pyrrole N-H group and the imine N atom of a neighbouring mol-ecule.

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{2-[(3,5-Dimethyl-2H-pyrrol-2-yl­idene-κN)(4-nitro­phen­yl)meth­yl]-3,5-dimethyl-1H-pyrrol-1-ido-κN}difluoridoboron

In an effort to discover novel and potential boron-dipyrromethene (BODIPY) dyes, the title compound, C(19)H(18)BF(2)N(3)O(2), was prepared from 2,4-dimethyl-pyrrole, 4-nitro-benzaldehyde and BF(3)·Et(2)O in a one-pot reaction. There are two independent mol-ecules, A and B, in the asymmetric unit in which the dihedral angles between the benzene ring and boron-dipyrromethene mean plane have signi...

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2010

ISSN: 1600-5368

DOI: 10.1107/s1600536810031867